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Sol-Gel Processing of colloid-based optical coatings

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Abstract

It is well established by manufacturers and users that optical coatings are generally prepared by the well known Physical Vapor Deposition (PVD) technology. In the authors' opinion sol-gel technology is an effective and competitive alternative. The aim of this paper is to emphasize on the sol-gel thin film work carried out at Centre d’Études de Limeil-Valenton (CEL-V) and concerning the technology for high power lasers. We will briefly discuss the chemistry of the sol-gel process, the production of optical coatings and the related deposition techniques. Finally, the paper describes the preparation and performance of sol-gel optical coatings we have developed to fulfill the requirements of a future 2-MJ/500-TW (351-nm) pulsed Nd:glass laser. This powerful laser is to be used for our national Inertial Confinement Fusion (ICF) program, to demonstrate at the laboratory scale, ignition of deuterium-tritium fusion fuel. Moreover, the aim of this article is, hopefully, to provide a convincing argument that coatings and particularly optical coatings, are some of the useful products available from sol-gel technology, and that exciting developments in other areas are almost certain to emerge within the coming decade.

© 1995 Optical Society of America

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