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The Femtosecond Dynamics of Aggregate Excitons in Liquids

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Abstract

Room temperature photon echo experiments show that optical dephasing in aggregates of dye molecules in solution is very slow (T2> 100 fs), due to motional narrowing over dynamic perturbations. By pump-probe experiments on multiple-exciton transitions the range of exciton delocalization was determined to be 18 molecules.

© 1994 Optical Society of America

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