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Multidimensional IR Spectroscopy of Site-Specific Hairpin Folding

A. W. Smith, H. S. Chung, Z. Ganim, and A. Tokmakoff

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Abstract

2D IR spectroscopy is used to probe the thermal unfolding of trpzip2 and PG-12, two β-hairpin peptides. The transient thermal unfolding of PG-12 is investigated with dispersed vibrational echo spectroscopy following a nanosecond temperature jump.

© 2006 Optical Society of America

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