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Conferences > UP > 2022 > Tu4A > Tu4A.49

Photoinduced Jahn-Teller distortion in crystals of Cu(I) phenanthroline complex

Vandana Tiwari, Ajay Jha, Hong-Guang Duan, and R. J. Dwayne Miller

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Abstract

We have studied the effect of lattice induced strained ligand geometry on the excited state dynamics of prototypical Cu(I) based photocatalyst in single crystals using fs-broadband transient absorption spectroscopy. Our results show faster intersystem crossing in crystals (~5 ps) as compared to the solution (~9 ps).

© 2022 The Author(s)

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