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The effect of methylation on the intersystem crossing dynamics of 2-thiouracil: Time-resolved photoelectron spectroscopy of 2-thiothymine

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Abstract

The ultrafast internal conversion (IC) and intersystem crossing (ISC) dynamics of 2-thiouracil (2TU) and 2-thiothymine (2TT) are studied with time-resolved photoelectron spectroscopy (TRPES) to investigate the effect of methylation on the deactivation mechanism.

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