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Progress in Understanding of Mechanisms of RE3+ Excited States Nonradiative Relaxation in Crystals

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Abstract

It was shown earlier [1-3], that the regularities of nonradiative relaxation (NR) of RE3+ excited states in oxide glass hosts are quantitatively described in the frames of model of dipole-dipole energy transfer to those high-frequency molecular oscillators of impurities or host, which overtones have the resonance with electronic transition. However the attempts [2,4] to apply this model to NR description in crystals gave contradictory results. It was pointed the satisfactory agreement of theory and experiment for Y3Al5O12, YAlO3 crystals [2], but for Y2O3 crystal situation was less consolatory [4].

© 1984 Optical Society of America

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