Picosecond Addition and β-Scission Reactions of Thiyl Radicals with Unsaturated Hydrocarbons

T. W. Scott

doi:10.1364/UP.1986.MF7

Topical Meeting on Ultrafast Phenomena
Technical Digest Series (Optica Publishing Group, 1986),
paper MF7
•https://doi.org/10.1364/UP.1986.MF7

Picosecond Addition and β-Scission Reactions of Thiyl Radicals with Unsaturated Hydrocarbons

T. W. Scott

International Conference on Ultrafast Phenomena 1986

Snowmass, Colorado United States
16–19 June 1986
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Chemistry/Biology Posters 1 (MF)

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T. W. Scott, "Picosecond Addition and β-Scission Reactions of Thiyl Radicals with Unsaturated Hydrocarbons," in Topical Meeting on Ultrafast Phenomena, Technical Digest Series (Optica Publishing Group, 1986), paper MF7.

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Abstract

It is well known that free radical reactions exhibit extreme product diversity through the action of a limited number of elementary steps. The most facile elementary reaction between sulfur centered thiyl radicals and hydrocarbon liquids is free radical addition to carbon-carbon double bonds (1). This is a rapid exothermic reaction which is generally reversible.

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